Electron mobility in liquid and supercritical helium measured using corona discharges: a new semi-empirical model for cavity formation.
نویسندگان
چکیده
Electron mobilities in supercritical and liquid helium were investigated as a function of the density. The mobilities were derived from I(V) curves measured in a high-pressure cryogenic cell using a corona discharge in point-plane electrode geometry for charge generation. The presented data spans a wide pressure and temperature range due to the versatility of our experimental set-up. Where data from previous investigations is available for comparison, very good agreement is found. We present a semi-empirical model to calculate electron mobilities both in the liquid and supercritical phase. This model requires the electron-helium scattering length and thermodynamic state equations as the only input and circumvents any need to consider surface tension. Our semi-empirical model reproduces experimental data very well, in particular towards lower densities where transitions from localised to delocalised electron states were observed.
منابع مشابه
Formation of Positively Charged Liquid Helium Clusters in Supercritical Helium and their Solidification upon Compression.
Positively charged ions were produced in supercritical helium at temperatures from 6 to 10 K and up to 2 MPa using a corona discharge. Their mobility was measured via current-voltage curves, and the hydrodynamic radius was derived using Stokes law. An initial increase and subsequent decrease of hydrodynamic radius was observed and interpreted in terms of growth, compression and solidification o...
متن کاملA Macroscopic Approach to Determine Electron Mobilities in Low-Density Helium
We have developed a macroscopic approach to predict electron mobilities and cavity sizes in liquid and supercritical helium using the free-volume concept. We demonstrate very good agreement with experimental electron mobility data and significant improvement with respect to the commonly used ‘bubble’ model, especially for low hydrostatic pressures. The reason for this advancement is the use of ...
متن کاملNew Method for Calculation Mixing Rule and Modification Semi-empirical Models for Solubility Modeling in Supercritical Solvent
The critical properties of a solute are required for modeling of the solubility by the equation of state. For many compounds, the critical properties are not available. So, group contribution method is utilized as a common method to estimate these properties. But, it leads to the consecutive errors in calculations of the solubility modeling. In this study, Soave-Redlish-Kowang (SRK) and Peng-Ro...
متن کاملNuclear-Charge Screening in Positronium Formation from Helium Atoms
An analytical treatment of the electron screening effect within an active-electron model is given for positronium formation from helium atoms. A first-order distorted wave approximation with correct boundary conditions is applied to evaluate the transition amplitude. In the range of impact energy for which the introduced perturbative approach is valid, both the total and differential cross sect...
متن کاملElectron mobility in semi-metal HgCdTe quantum wells: dependence on the well width.
Energy spectra, carrier concentration and electron mobility are numerically modeled in intrinsic and n-type semi-metal HgCdTe quantum wells at T = 77 K. We present results for the electron mobility calculated in a model incorporating electron scattering on longitudinal optical phonons, charged impurities, and holes, and including the 2D electron gas screening for all mentioned scattering mechan...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical chemistry chemical physics : PCCP
دوره 13 2 شماره
صفحات -
تاریخ انتشار 2011